Where solanine concentrates in an affected potato
Solanine does not spread evenly throughout a potato. It concentrates primarily in the green areas and in the layer of flesh just beneath the skin of affected tubers. The deeper, starchy interior of the potato typically contains far lower levels.

This is why the practical food safety advice focuses on the skin and the immediate sub-surface tissue. Peeling away the green parts generously — not just skimming the surface — removes the zones where the toxin is most concentrated.
The eyes and sprouts of a potato also naturally contain higher solanine levels, even in potatoes that show no green color at all. Any potato that has begun to sprout should have those growths removed thoroughly before cooking.
How light exposure happens — and how to prevent it
Green potatoes are a direct result of improper storage. Exposure to light — whether sunlight, fluorescent supermarket lighting, or even a bright kitchen counter — is enough to set off both chlorophyll and solanine production over time.

Storing potatoes in a cool, dark, and well-ventilated place is the most effective way to prevent greening. A paper bag, a dark cupboard, or a cellar are all suitable options. Plastic bags that trap moisture should be avoided, as they accelerate sprouting.
Buying potatoes in opaque bags rather than clear packaging also reduces their light exposure before they reach your home. Once stored correctly, potatoes can remain in good condition for several weeks without developing significant greening or solanine build-up.
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